Structural and hyperfine magnetic properties of primary steelmaking slag

Marlon I. Valerio-Cuadros; A. G.Bustamante Dominguez; R. A. Valencia-Bedregal; L. E. Borja-Castro; S. M.Espinoza Suarez; H. A. Cabrera-Tinoco; C. H.W. Barnes; L. De Los Santos Valladares

doi:10.1007/s10751-022-01797-z

Structural and hyperfine magnetic properties of primary steelmaking slag

Marlon I. Valerio-Cuadros
, A. G.Bustamante Dominguez
, R. A. Valencia-Bedregal
, L. E. Borja-Castro
, S. M.Espinoza Suarez
, H. A. Cabrera-Tinoco
, C. H.W. Barnes
, L. De Los Santos Valladares

Faculty of Engineering

Research output: Contribution to journal › Original Article › peer-review

4 Scopus citations

Abstract

Nowadays there is a high interest in the recovery of industrial steel waste into useful by-products. For that purpose, it is important to know the physical and chemical properties of steel slag in order to better understand its characteristics and thus seek applications. In this work, we study primary steel slag formed in an electric arc furnace (EAF). Here we present the structural characterization and magnetic properties of the slag performed by X-ray fluorescence spectroscopy (XRF), X-ray diffractometry (XRD), scanning electron microscopy (SEM), magnetic measurements and Mössbauer spectroscopy. The elements Zn, Fe, Cl, Ca, and K and the phases Fe₃O₄, Zn₅(OH)₈Cl₂.H₂O, ZnO, and KCl were identified by XRF and XRD, respectively. Mössbauer spectroscopy at room temperature shows one doublet typical for Fe²⁺, and sextets corresponding to Fe₃O_4, and Fe₂O₃. ⁵⁷Fe-Mössbauer spectroscopy appears as a necessary tool in metallurgical slag research.

Original language	American English
Article number	11
Journal	Hyperfine Interactions
Volume	243
Issue number	1
DOIs	https://doi.org/10.1007/s10751-022-01797-z
State	Indexed - Dec 2022

Bibliographical note

Publisher Copyright:
© 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG.

Keywords

Electrical arc furnace
Mössbauer spectroscopy
Steelmaking slag
X-ray diffraction

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10.1007/s10751-022-01797-z

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title = "Structural and hyperfine magnetic properties of primary steelmaking slag",

abstract = "Nowadays there is a high interest in the recovery of industrial steel waste into useful by-products. For that purpose, it is important to know the physical and chemical properties of steel slag in order to better understand its characteristics and thus seek applications. In this work, we study primary steel slag formed in an electric arc furnace (EAF). Here we present the structural characterization and magnetic properties of the slag performed by X-ray fluorescence spectroscopy (XRF), X-ray diffractometry (XRD), scanning electron microscopy (SEM), magnetic measurements and M{\"o}ssbauer spectroscopy. The elements Zn, Fe, Cl, Ca, and K and the phases Fe3O4, Zn5(OH)8Cl2.H2O, ZnO, and KCl were identified by XRF and XRD, respectively. M{\"o}ssbauer spectroscopy at room temperature shows one doublet typical for Fe2+, and sextets corresponding to Fe3O4, and Fe2O3. 57Fe-M{\"o}ssbauer spectroscopy appears as a necessary tool in metallurgical slag research.",

keywords = "Electrical arc furnace, M{\"o}ssbauer spectroscopy, Steelmaking slag, X-ray diffraction",

author = "Valerio-Cuadros, \{Marlon I.\} and Dominguez, \{A. G.Bustamante\} and Valencia-Bedregal, \{R. A.\} and Borja-Castro, \{L. E.\} and Suarez, \{S. M.Espinoza\} and Cabrera-Tinoco, \{H. A.\} and Barnes, \{C. H.W.\} and Valladares, \{L. De Los Santos\}",

note = "Publisher Copyright: {\textcopyright} 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG.",

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month = dec,

doi = "10.1007/s10751-022-01797-z",

language = "American English",

volume = "243",

journal = "Hyperfine Interactions",

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TY - JOUR

T1 - Structural and hyperfine magnetic properties of primary steelmaking slag

AU - Valerio-Cuadros, Marlon I.

AU - Dominguez, A. G.Bustamante

AU - Valencia-Bedregal, R. A.

AU - Borja-Castro, L. E.

AU - Suarez, S. M.Espinoza

AU - Cabrera-Tinoco, H. A.

AU - Barnes, C. H.W.

AU - Valladares, L. De Los Santos

PY - 2022/12

Y1 - 2022/12

N2 - Nowadays there is a high interest in the recovery of industrial steel waste into useful by-products. For that purpose, it is important to know the physical and chemical properties of steel slag in order to better understand its characteristics and thus seek applications. In this work, we study primary steel slag formed in an electric arc furnace (EAF). Here we present the structural characterization and magnetic properties of the slag performed by X-ray fluorescence spectroscopy (XRF), X-ray diffractometry (XRD), scanning electron microscopy (SEM), magnetic measurements and Mössbauer spectroscopy. The elements Zn, Fe, Cl, Ca, and K and the phases Fe3O4, Zn5(OH)8Cl2.H2O, ZnO, and KCl were identified by XRF and XRD, respectively. Mössbauer spectroscopy at room temperature shows one doublet typical for Fe2+, and sextets corresponding to Fe3O4, and Fe2O3. 57Fe-Mössbauer spectroscopy appears as a necessary tool in metallurgical slag research.

AB - Nowadays there is a high interest in the recovery of industrial steel waste into useful by-products. For that purpose, it is important to know the physical and chemical properties of steel slag in order to better understand its characteristics and thus seek applications. In this work, we study primary steel slag formed in an electric arc furnace (EAF). Here we present the structural characterization and magnetic properties of the slag performed by X-ray fluorescence spectroscopy (XRF), X-ray diffractometry (XRD), scanning electron microscopy (SEM), magnetic measurements and Mössbauer spectroscopy. The elements Zn, Fe, Cl, Ca, and K and the phases Fe3O4, Zn5(OH)8Cl2.H2O, ZnO, and KCl were identified by XRF and XRD, respectively. Mössbauer spectroscopy at room temperature shows one doublet typical for Fe2+, and sextets corresponding to Fe3O4, and Fe2O3. 57Fe-Mössbauer spectroscopy appears as a necessary tool in metallurgical slag research.

KW - Electrical arc furnace

KW - Mössbauer spectroscopy

KW - Steelmaking slag

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/85124088587

U2 - 10.1007/s10751-022-01797-z

DO - 10.1007/s10751-022-01797-z

M3 - Original Article

AN - SCOPUS:85124088587

SN - 0304-3843

VL - 243

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 1

M1 - 11

ER -

Structural and hyperfine magnetic properties of primary steelmaking slag

Abstract

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